Q&A

(2017) Question 37: What programs have you implemented to improve reliability and life of the coke drums including inspection and maintenance?

The refining industry is continuously experiencing coke drum problems and failures due to low cycle fatigue. The two main problems caused by the cyclical operation of coke drums are shell bulging and shell/skirt circumferential weld-seam cracking.

(2017) Question 38: How do you monitor coke drum overhead lines to determine when cleaning is required? What cleaning techniques are effective and which are ineffective?

Higher pressure drop reduces gasoil yields in the coker fractionator and profitability for the refinery. Establish graphs that demonstrate the relationship between pressure drop and yield loss and make them visible to the organization.

(2017) Question 39: What procedures and techniques are you currently using to monitor and control cyanide corrosion on coker overhead circuit and light ends units?

Cyanide corrosion is a hydrogen permeation phenomenon on steel that tends to cause cracking, commonly at high stress zones, and possible blistering on “dirty” base steel. Finding cyanide in an overhead circuit does not mean there is a problem.

(2017) Question 40: What crude properties and process conditions are you monitoring as part of a crude slate change?

Crude quality should be compared against similar crudes already approved for processing at the refinery. Obtain crude samples, when possible, to confirm the properties listed in the assay. Ensure that sufficient sample volume (three to five quarts is recommended) to pre-test for crude compatibility with other crudes in your tank farm.

(2017) Question 41: What are some of your operating practices used to mitigate incursion of water slugs in crude feed from tankage? Are there any early warning devices or procedures currently being used successfully?

Plugs of water are problematic, in terms of causing desalting and crude column upsets. Pockets of water can form in the tank due to the characteristics of the crude. The primary defense is to minimize water in crude oil; but with current upstream practices, we know water will enter in with the crude. Having systems in place to reduce, mitigate, and handle water intrusion is important to maintain stable crude unit operations.

(2017) Question 42: What water sources are you using for desalter waterwash, and what are the advantages and disadvantages of each? What role does desalter waterwash source and injection location play in desalter performance?

Over the years, we have established several Best Practices concerning desalter wash water rates, quality, injection locations, and sources that – when utilized – help ensure optimum crude oil desalting.

(2010) Question 49: What testing procedures do you use for emergency shutdown valves? What are the parameters you measure and what are acceptable values?

The appropriate required testing of emergency shutdown valves is included in each Marathon refinery’s Mechanical Integrity (MI) program, complying with OSHA’s Process Safety Management regulation and EPA’s Risk Management Plan regulation.

(2010) Question 50: Chemical cleaning of towers and vessels prior to entry is being used to reduce time to entry. What practices are you employing and how much time is saved?

Our chemical cleaning practices for Crude/Vacuum and Coking units have evolved over many years. The starting point in most cases, after feed is out and the unit has circulated down, cooled and pumped out, is a flush with diesel or LCO followed by a good steamout.

(2010) Question 51: In your experience, what are the implications on coker heater run length and coke drum operations with the following feedstock quality: Contaminants (Na, Ca), low saturates or high asphaltenes, crude compatibility, solvent deasphalt (SDA) pitch, low asphaltenes and high saturates?

There are at least three main mechanisms under which the heater tubes become fouled: •Inorganic material deposition or precipitation, •Rapid asphaltene precipitation, •Coke formation

(2010) Question 52: What areas of a delayed coker are susceptible to naphthenic acid corrosion? How do you determine the maximum allowable TAN for these areas?

The primary areas of concern include: •Coker feed circuit above 450 °F •Bottom section of the fractionator, including internals •Heater charge pumps and associated piping •Heater tubes.

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