Q&A

Question 3: Carbonate stress corrosion cracking (CSCC) has been identified as a cause of failure in FCC main fractionator overhead systems. What changes in feed quality, unit operation, or configuration would lead to increased risk of CSCC? What parameters do you monitor to determine whether a system is susceptible to CSCC? Has the problem been significant enough to warrant either comprehensive PWHT in potentially affected areas or localized PWHT when problem areas are identified?

Carbonate stress corrosion cracking, CSCC, is characterized by inter-granular, sometimes branchy, scale-filled cracks. It is believed that ammonium carbonate is the main contributor to the cracking mechanism.

Question 5: What is the shortest possible time between oil out and entry for maintenance on large inventory, high capacity FCC units? How is this achieved?

With FCCs at 27,000 bpd and 9,000 bpd capacity, neither of our units really qualifies for high throughput or large capacity. However, in discussions amongst the members of the panel, we found that throughput and inventory are not necessarily good indicators of how quickly you can move oil-out to maintenance-in.

Question 6: Some CO and waste heat boilers operate with bypass stacks separated by seal pots or isolation valves. Maintenance of these seal systems can be expensive and these seal systems can be sources of poor reliability. What design upgrades and operating practices have enabled you to eliminate these bypass systems?

Holly Refining continues to use bypass stacks with diversion valves at both of our refineries. Those stacks and diversion valves are allowed by permit and we use them during startup/shutdown manning upset conditions. Both our Operations and Maintenance groups are assigned weekly preventative maintenance tasks to ensure operability when we do have to throw these valves.

Question 7: Is your company either considering, or actually implementing, FCC projects that include reduced CO2 emissions (greenhouse gas reduction-GHGR) as an offset/credit?

We do not have any current FCC projects that plan on utilizing some form of CO2 offset or credit in the emissions analysis. ConocoPhillips has performed a limited modeling study to evaluate the effect of operational changes on CO2 emissions from the FCC. Also, the study indicated that there is very little you can do to reduce overall emissions without also overall significantly reducing unit throughput or conversion.

Question 10: What is your recent experience regarding the maximum level of equilibrium catalyst metals (Ni, V, Na, Fe, Ca) in FCC units processing residual feedstocks? Have there been any recent improvements in vanadium passivation technologies? At nickel levels approaching 10,000 ppm, have you experienced increased catalyst deactivation as evidenced by lower equilibrium zeolite surface area?

Here we see data regarding one of our FCCUs that operates at e-cat nickel levels exceeding 10,000 ppm. We observe that the MAT generally remains within the same range until high e-cat nickel concentrations are approached.

(2012) Question 76: The check valve on the air blower discharge line is designed to protect the blower from hot catalyst that backs into it when the blower fails. What type of valve is used in this service, where is it located, and what is done to ensure that it closes properly?

UOP specifies two special check valves in the blower discharge line. The first special check valve is installed a minimum distance from the blower discharge downstream in the snort (or anti-surge) valve in a horizontal pipe run.

(2012) Question 77: For our emergency interlock system, we employ two-out-of-three voting systems for slide valve differential pressure transmitters. We use dedicated transmitter taps for each transmitter, but we get inconsistent readings. What can we do, regarding design and maintenance, to ensure that these transmitters read more consistently? What should we do if we are unable to achieve consistent readings?

To obtain a more consistent reading, plant personnel should examine three phases: the transmitter, its physical location, and its instrument gas system. As for the transmitter, the technician should analyze it to ensure that it is within the accuracy specified by the manufacturer.

(2012) Question 78: What inputs or trips are typically included in FCC flue gas expanders and CO (carbon monoxide) boilers' safety interlock systems? Are there any governing standards [(e.g., API and NFPA (National Fire Protection Association)] that apply?

I would like to address this question as two different parts, beginning with the flue gas expanders. BP has three flue gas expanders in its system. These expanders are all set up with slightly different configurations. We have one FCCU flue gas expander that is directly coupled to the main air blower.

Question 79: What tools are being used to monitor FCC performance? What are the key performance indicators and expectations?

These are two broad categories for the use of these indicators. The first category is capacity utilization and yield performance, which covers process performance, operating constraints, and optimal use of any inherent design margins.

(2012) Question 80: We are considering severe hydrotreating of our FCC feed. What yield shifts or unusual operating problems might we expect? What can be done to address these issues?

Processing Hydrotreated Feed: First of all, let’s define what ‘severely’ hydrotreated feed means. One unit in our system hydrotreats the feed down to 50 ppm sulfur and 50 ppm nitrogen, so you can see that processing that type of feedstock has tremendous yield benefits.

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