Q&A

(2016) Question 6: What is your experience with having a vent depropanizer off-gas unit in order to manage tower pressure, and what might be the cause of and solution to the problem?

The typical and probably most obvious driver for the need to vent from a depropanizer column is the presence of non-condensable gases. Most commonly, this is ethane and ethylene that come in with the feed.

(2016) Question 7: How is propane content in the refrigeration loop optimized against the compressor capacity to minimize contractor temperature? Do you have a good process model to predict the optimum propane content?

There is an optimum propane concentration in the refrigerant that will allow the alkylation unit to operate at a maximum alkylate throughput when the unit is up against limitations of both the compressor and the reaction zone heat removal capability. That optimum concentration of propane will vary from unit to unit and can be different seasonally. It can also be different from night to day or if exchangers are fouled, etc.

(2016) Question 10: What strategies do you employ to meet cycle-length targets in naphtha hydrotreaters that are reaching catalyst activity limits due to capacity increases or feedstock quality decreases?

To increase cycle length on an NHT hydrotreater, the refinery needs to understand the contaminants that the reactor must handle and optimize the bed loading to maximize cycle length, as well as have the ability to handle the contaminant.

(2016) Question 27: What methods do you use to reduce particulate loading on or debottleneck of existing filtration equipment in a HPU unit without reducing catalyst cycle life?

The use of feed filters is highly recommended, but it is important to choose a filter size that will be manageable; meaning that if a 5-micron filter is used, it will most likely have to be replaced or backflushed several times per day, which is not practical. However, if a too-large filter size is used, it will not be effective. The only way to reduce the particulate loading on a feed filter is to increase the filter size, thus allowing more material to slip through.

(2016) Question 28: Our hydrotreating unit continues to suffer from pressure drop issues. Multiple graded-bed schemes have provided incremental improvements. What other successful solutions to further mitigate pressure drop buildup do you employ?

Solving reactor pressure drop issues has been a decades-long ongoing effort, and Haldor Topsoe has been a pioneer within this area since the early 80s when Haldor Topsoe first commercialized highly effective catalytically active grading products.

(2016) Question 29: What level measurement technology is used in the hydrotreater high-pressureseparator? Is the recommendation different if the unit runs in block modes (with feeds of varying densities)? What design considerations should be taken into account when selecting a high-pressure separator level control valve?

Like any instrumentation, there are advantages and disadvantages for different types of instrumentation in almost any service; therefore, there is no single choice of a Best Practice in all situations. Experiences vary from refiner to refiner, and even sometimes from unit to unit within a refinery depending on many factors, both technical and non-technical. It is important to understand the choices within both contexts. As the non-technical factors –such as instrument technician experience, refinery standards, etc. –are too general, they will not be addressed directly.

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Q&A

(2016) Question 6: What is your experience with having a vent depropanizer off-gas unit in order to manage tower pressure, and what might be the cause of and solution to the problem?

(2016) Question 7: How is propane content in the refrigeration loop optimized against the compressor capacity to minimize contractor temperature? Do you have a good process model to predict the optimum propane content?

(2016) Question 10: What strategies do you employ to meet cycle-length targets in naphtha hydrotreaters that are reaching catalyst activity limits due to capacity increases or feedstock quality decreases?

(2016) Question 27: What methods do you use to reduce particulate loading on or debottleneck of existing filtration equipment in a HPU unit without reducing catalyst cycle life?

(2016) Question 28: Our hydrotreating unit continues to suffer from pressure drop issues. Multiple graded-bed schemes have provided incremental improvements. What other successful solutions to further mitigate pressure drop buildup do you employ?