Q&A

(2018) Question 1: What are the benefits of alumina treating in sulfuric acid alkylation and HF alkylation? Has this technology been proven commercially?

In the sulfuric acid alkylation process, droplets of acid are found in the effluent stream from the reactor. These droplets, which are formed primarily from the alkylation chemistry itself and the formation of intermediates, are small and stable and cannot be removed by gravity settling and / or coalescing alone.

(2018) Question 2: What metallurgy works well and does not work well for use in alkylation units? In what applications does the alternate metallurgy perform better/worse?

The standard metallurgy for use throughout HF alkylation units is carbon steel. Showing a high degree of corrosion resistance in both low and very high acid concentrations, carbon steel is also useful for its relatively low cost compared to more exotic materials.

(2018) Question 3: What type of release mitigation safety systems do you use for sulfuric acid and HF alkylation units?

Sulfuric acid alkylation units do not require the robust safety systems as the HF Alky units since sulfuric acid is a liquid at atmospheric conditions. The release mitigation safety systems typically used are curbed and/or diked areas to contain the liquid sulfuric acid in event of a leak.

(2018) Question 9: Are you adding unusual feeds to catalytic condensation or oligomerization units?

Refiners have been pursuing the use of more atypical feeds to their olefin oligomerization units for various reasons. Units have historically operated on FCC LPG cuts, but an interest to process Coker LPGs or even heavier FCC olefins have begun.

(2018) Question 25: Coke drum integrity can be compromised due to the use of feed side entry devices. What is your experience with drum roundness upon inspection?

Coke drum integrity is typically dominated by low cycle fatigue. Imposed stresses due to thermal gradients during drum warming, water quenching and the contraction of the drum while full of coke can result in stresses higher than the yield stress of the coke drum metal.

(2018) Question 26: How do you monitor furnace convection section fouling? What mitigation steps do you implement?

Monitoring the flue gas temperature leaving the process convection section is a simple method of tracking the heat transfer in the convection section. The excess air needs to be taken into consideration as a higher O2 concentration will shift heat transfer into the convection section and causes the total quantity of flue gas to increase.

(2018) Question 27: What is your experience with chemical treatment to reduce furnace coking?

For conventional fouling, which is the result of asphaltene destabilization due to temperature, chemical treatment programs have not been effective for Coker heaters. For premature asphaltene precipitation due to resid compatibility concerns, chemical treatment programs have been effective in reducing or eliminating fouling.

(2018) Question 49: As the demand for higher octane gasoline components increases and lobbying for a 95 RON gasoline standard continues, how are you adjusting your operations to meet the market demand? What FCC specific changes do you make to produce higher octane gasoline components?

Refiners are optimizing their gasoline blend components to maximize high octane components. Alkylate and reformate yields are becoming increasingly important, as well as minimizing low octane component yields. The emergence of tight oil feeds has created an increase in low octane natural gasoline and LPG saturate production.

(2018) Question 50: Butylene demand and prices in relation to other refined products reached a record level in 2017. What caused it and what can we do in the FCC to produce more butylenes?

Higher demand for butylene is result of octane shortage in the gasoline market stemming from several main causes.

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