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These digital transcripts are meant to share information on process safety practices in order to help improve process safety performance and awareness throughout industry. The goal is to capture and share knowledge that could be used by other companies or sites when developing new process safety practices or improving existing ones. The documents being shared have been used by an industry member, but this does not mean it should be used or that it will produce similar results at any other site. Rather, it is an option to consider when implementing or adjusting programs and practices at a site. ​

BY THEMSELVES, THESE DIGITAL TRANSCRIPTS ARE NOT STANDARDS OR RECOMMENDED PRACTICES. THEY ARE NOT INTENDED TO REPLACE SOUND ENGINEERING JUDGMENT. THEY DO NOT PRECLUDE THE USE OF ALTERNATIVE METHODS THAT COMPLY WITH LEGAL REQUIREMENTS. A SUBJECT MATTER EXPERT SHOULD BE CONSULTED PRIOR TO DETERMINING WHETHER A PRACTICE CAN BE USED IN ANY SPECIFIC SITUATION. 

​

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(2016) Question 6: What is your experience with having a vent depropanizer off-gas unit in order to manage tower pressure, and what might be the cause of and solution to the problem?

The typical and probably most obvious driver for the need to vent from a depropanizer column is the presence of non-condensable gases. Most commonly, this is ethane and ethylene that come in with the feed.
Read more

(2016) Question 7: How is propane content in the refrigeration loop optimized against the compressor capacity to minimize contractor temperature? Do you have a good process model to predict the optimum propane content?

There is an optimum propane concentration in the refrigerant that will allow the alkylation unit to operate at a maximum alkylate throughput when the unit is up against limitations of both the compressor and the reaction zone heat removal capability. That optimum concentration of propane will vary from unit to unit and can be different seasonally. It can also be different from night to day or if exchangers are fouled, etc.
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(2010) Question 85: What is the typical range that you employ for iron content on FCC equilibrium catalyst? What methods are available to determine how iron is accumulated on the catalyst surface? How does the distribution of iron on the catalyst surface impact the FCC operation, yield structure and emissions?

There are several methods available to quantify iron contamination on catalyst. Scanning Electron Microscopy (SEM) pictures are a valuable means to qualitatively assess iron laydown morphology on the catalyst particle.
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(2010) Question 86: In your experience, what are catalyst best practices to shift FCC yields rapidly between gasoline and diesel maximization and then back again? Many catalyst suppliers are recommending blended catalyst systems. Do you believe this catalyst/additive blending is the best approach?

Co-catalysts are a new product category providing the refiner with the flexibility to change the product slate of the FCC without changing the FCC catalyst. Changing between a maximum gasoline co-catalyst and a maximum LCO co-catalyst will allow the refiner to rapidly capture the most favorable economics at all times – maximizing FCC profitability. Co-catalysts are added to the base catalyst to rapidly change the core performance of the FCC.
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(2010) Question 87: In your experience, how does catalyst activity affect the catalyst's coke selectivity and the FCCU's delta coke? How are the coke selectivity and delta coke related? Lastly, discuss how to determine the proper activity to maximize conversion.

When designing an FCC catalyst, one must consider coke selectivity, delta coke and total coke yield. Coke selectivity is the relative coke-making tendency of the catalyst, or in other words, a catalyst with good coke selectivity produces higher conversion per unit of coke make than the reference catalyst.
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(2018) Question 1: What are the benefits of alumina treating in sulfuric acid alkylation and HF alkylation? Has this technology been proven commercially?

In the sulfuric acid alkylation process, droplets of acid are found in the effluent stream from the reactor. These droplets, which are formed primarily from the alkylation chemistry itself and the formation of intermediates, are small and stable and cannot be removed by gravity settling and / or coalescing alone.
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