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(2010) Question 63: Certain crudes are treated with H2S scavenger to meet a 10 ppm or less specification in the vapor space. In your experience, what is the disposition of the reacted and unreacted scavenger additive through the crude unit? Will this product and/or associated byproducts create corrosion or product quality issues in the crude unit or downstream units?

The majority of H2S scavengers used today are water-soluble, cyclic amines which can quickly react with H2S, forming a water-soluble reaction product. However, these amine-based scavengers are not without potential problems. As formulated, these scavengers often contain un-reacted amines.
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(2018) Question 31: How does emulsion breaker performance compare when injected in the crude or wash water? What is your method to inject emulsion breaker for 2 stage desalters?

For the desalter system as a whole, the typical emulsion breaker is injected into the crude stream as far upstream as possible in order to provide intimate contact. In this case, the emulsion breaker is one that has a hydrocarbon solvent and so is hydrophilic which wants to stay in the oil phase. There are cases where injecting this emulsion breaker into the water phase can help reduce the impact of surfactants that surround the water droplets.
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(2018) Question 32: Have you developed processes to successfully extract the emulsion layer from the desalter, so the emulsion can be treated separately? Please describe your chemical treatment programs and equipment that have been implemented successfully to treat this extracted emulsion.

Emulsion extraction headers, sometimes called cuff headers, have been an option and have been installed in desalters for decades. The removal of the emulsion layer solves one problem and creates another as this emulsion layer can be very difficult to treat.
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(2018) Question 41: What effective practices do you deploy to improve the removal of inorganic contaminants in crude such as iron and calcium? What has been the industry success rate with these practices?

Cracked feedstocks can be introduced into the crude unit from several sources; the most common of which in North America are diluted bitumen from Canadian sources, diluted crude oils from South American sources, and slop streams from cracking units onsite that are recycled into the reprocessed slop oil blended into the crude unit feedstream.
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