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These digital transcripts are meant to share information on process safety practices in order to help improve process safety performance and awareness throughout industry. The goal is to capture and share knowledge that could be used by other companies or sites when developing new process safety practices or improving existing ones. The documents being shared have been used by an industry member, but this does not mean it should be used or that it will produce similar results at any other site. Rather, it is an option to consider when implementing or adjusting programs and practices at a site. ​

BY THEMSELVES, THESE DIGITAL TRANSCRIPTS ARE NOT STANDARDS OR RECOMMENDED PRACTICES. THEY ARE NOT INTENDED TO REPLACE SOUND ENGINEERING JUDGMENT. THEY DO NOT PRECLUDE THE USE OF ALTERNATIVE METHODS THAT COMPLY WITH LEGAL REQUIREMENTS. A SUBJECT MATTER EXPERT SHOULD BE CONSULTED PRIOR TO DETERMINING WHETHER A PRACTICE CAN BE USED IN ANY SPECIFIC SITUATION. 

​

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(2008) Question 98: What metallurgy are you using for mesh pads in reformer compressor suction knockout drums? How often are the mesh pads inspected and how often are they replaced? Are the same criteria used for mesh pads in product separators?

Question 98 What metallurgy are you using for mesh pads in reformer compressor suction knockout drums? How often are the mesh pads inspected and how often are they replaced? Are the same criteria used for mesh pads in product separators? Rick Grubb (Chevron USA) We typically use 304 SS demister pads in the refinery and inspect them every 10 years. In reforming service we have been using Tefzel demister pads and have been replacing them approximately every dump and screen due to separator internal inspections. If we go into the vessel we go ahead and inspect the mesh pad, but assume before opening the vessel that the pad will need replacing. The Tefzel pads have greatly increased the reliability such that we don’t find mesh pad pieces in the compressors anymore. We have been contemplating using co-knit pads (synthetic fiber inter-woven with a SS fiber), but have not done so yet.
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(2019) Question 8: Where is salt (NH4Cl or (NH4)2S) fouling most likely to occur? What are common practices for monitoring and mitigating?

ABIGAIL SLATER (HollyFrontier)
Salting typically occurs in the reactor effluent exchangers (shell and tube and fin fans), recycle and net gas compressors, and product stabilizer overhead system (top trays, overhead condenser, etc.). Common monitoring practices on exchangers and fin fans can be

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(2019) Question 9: How do you track chloride in liquid/gas/LPG? What are your criteria for replacing adsorbent in chloride treaters?

DAVINDER MITTAL (HPCL Mittal Energy)
Chlorides have been a long standing issue in catalytic reformer operation. Until a few years ago, the focus on preventing operational problems from the chloride compounds in the catalytic reformer product stream was to remove HCl.  More recently, a growing

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(2019) Question 10: What causes metal-catalyzed coking (MCC) that obstructs catalyst circulation in CCR reformers? What actions do you take to mitigate MCC formation?

BILL KOSTKA (AXENS NORTH AMERICA)
Metal-catalyzed coke (MCC) formation typically occurs on 3d valence transition metals such as iron and nickel.  Under CCR-like conditions of low hydrogen partial pressure (less than about 620 kpa), high temperature (more than about 480 °C) and low or stagnant flow

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(2019) Question 11: Where are your liquid-phase chloride treaters installed for reforming units? What are the advantages of each location?

BILL KOSTKA (AXENS NORTH AMERICA)
Liquid-phase Cl treaters are typically used in three locations for reforming units.

Treating the unstabilzed reformate stream provides several advantages.  The stream is heated upstream of the stabilizer column which ensures that any ammonium chloride is

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(2019) Question 14: What are your strategies to reduce alky acid consumption?

ABIGAIL SLATER (HollyFrontier)
The most impactful parameter affecting alky acid consumption is feed quality. Reducing feed contamination will greatly reduce acid consumption. There are also operational changes that can be made to reduce acid consumption, but the biggest impact will be feed

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(2008) Is your company planning to install modified HF acid capability (usage of the volatility suppressing additive)? What are the incentives for doing this? What alternatives have you considered?

In March 2006, in our continuing effort to support safe, reliable, and environmentally sound operation, we announced our plans to apply for a permit to independently initiate an alkylation process improvement project in our Philadelphia HF alkylation unit.
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(2008) Question 70: How frequently do you have fires on reformer reactor flanges? What bolting techniques and gasket types do you use to prevent leaks? What other fixes, such as flange resurfacing, have you employed? Do you use steam ri

GRUBB (Chevron USA, Inc.) Chevron has had some experience with flange fires in the past, so I’ve consulted with Dave Reeves, our corporate expert and also our Best Practice that we’ve developed for this. I know that I said temporary fixes up on the slide, but it’s not really a temporary fix.
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(2008) Question 71 Is your company planning to install modified HF acid capability (usage of the volatility suppressing additive)? What are the incentives for doing this? What alternatives have you considered?

METKA (Sunoco, Inc.) In March 2006, in our continuing effort to support safe, reliable, and environmentally sound operation, we announced our plans to apply for a permit to independently initiate an alkylation process improvement project in our Philadelphia HF alkylation unit.
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(2008) Question 72 What feed contaminants can lead to metal corrosion in both sulfuric acid and HF alkylation units? What operating conditions promote corrosion? What do you do to reduce corrosion and/or remove contaminants?

GRUBB (Chevron USA, Inc.) I’ve consulted Gary Ash, the Pascagoula local expert, and Steve Mather, who is the corporate expert. They relayed to me that acid is still the biggest problem and not really necessarily the contaminants; but where the feed contaminants come in, they can make the acid more

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