Q&A

(2012) Question 16: What is the commercial experience on the use of H2 membranes in hydrotreaters or hydrocrackers for H2 recovery? What is a reasonable membrane life given the sensitivity to fouling and temperature changes?

At the Denver Refinery, we have a few hydrogen separation membranes. We call them our hydrogen purification unit. Our #3 HDS, which is currently our ULSD unit, was previously a gas oil hydrotreater until we revamped it in 2006. So, the HPUs (hydrogen purification units) were in consistent service from 1990 to 2006.

(2012) Question 17: Now that natural gas prices are low in North America, what options are available to increase refinery volume gain and product quality by exploiting low-cost hydrogen? Is the low hydrogen production cost impacting the economics between the selection of coking or hydrocracking?

There were a number of questions this year that requested information about how to effectively utilize low-cost hydrogen to increase refinery volume yields.

(2012) Question 18: What are the economic incentives to justify upgrading reactor internals? What techniques have been utilized to assess the performance of existing reactor internals?

The primary incentive is catalyst life and the ability to meet turnaround intervals. Gas and liquid distribution improvement results in increased catalyst performance and potentially longer catalyst life. Reactor internal upgrades may consist of quench decks, mixing chambers, and improved liquid distributor trays.

(2012) Question 19: Since API-932 (Waterwash Best Practices) was published, what has been the impact on reactor effluent air cooler washwater system design and reliability? Are there any active or ongoing studies to improve waterwash systems, in addition to API-932?

The question of issues associated with waterwash has been discussed since the API-932 was issued. This first slide gives a little chronology of some of the documents.

(2012) Question 20: What is the industry experience with managing cracked feedstocks to avoid hydrotreater problems such as fouling, and pressure drop?

Some of the mitigation options can be summarized in four areas. The first is feed logistics. We would say that if you are going to handle this, you need to do as much direct feeding as possible.

(2012) Question 21: High pressure strippers are an option for controlling VOCs in process condensate and managing export steam quality in a steam methane reformer hydrogen plant. What types of pH controls are being used?

Most hydrogen plants take the process condensate, send it to a deaerator to clean it up, and then reuse that condensate while mixing it with some boiler feedwater internally. There are configurations that have high pressure strippers where they will bring in some steam and do some initial stripping.

(2012) Question 22: What preventative maintenance program is applied to safety instrumented systems on a steam methane reformer that are Safety Integrity Level (SIL) rated?

Safety instrumented systems (SIS), as defined by ANSI/ISA-84.00.01-2004 Part 1(IEC-61511-1 Mod), are required to have components functionally tested and/or replaced/ refurbished under preventative maintenance (PM) to provide the reliability required to have a Safety Integrity Level (SIL) rating. SIL-rated safety systems are often required when a greater degree of protection layers is required then that offered by standard design.

(2012) Question 23: What are some options for increasing the cetane index (CI) of diesel to more easily meet export market requirements?

Cetane improvement chemistry mechanisms available to us are aromatic saturation and naphthenic ring opening (hydrocracking), both of which allow us to further take advantage of low-cost hydrogen to provide cetane upgrades and liquid volume gains.

(2012) Question 24: Given the potential consequences of back flow in high pressure hydroprocessing services, such as furnace tube rupture and pump shutdown, what layers of protection are being employed to reduce risk?

Our layers of protection are very similar here in that we have trip valves activated by SIL-rated instruments and which are only SIL-rated as required. And of course, we have basic process controls and critical alarm systems. In some, but not all, cases, we do have check valves downstream of our furnaces. That is not a standard at all our sites. However, on some sites, we are consistent about having check valves downstream of our furnaces.

(2012) Question 25: What is your philosophy for mitigating fouling and corrosion in reactor effluent cooler systems in hydrotreater or hydrocracker units during a short-term washwater pump failure scenario? How much time is allowed before initiating a unit shutdown?

Chevron developed a rough set of internal guidelines that determine the allowable time to run without water injection. The guidelines are based upon ammonium bisulfide (NH4HS) concentration. For units that run at what we call low severity, which is zero to 3% NH4HS, we will allow a couple of days of operation without water injection. As the normal NH4HS concentration of the operating unit sour water increases, we allow progressively less time to run without water injection.

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