Question 14: What are the advantages and challenges associated with alkylating amylenes?
Kurt Detrick (UOP)
Some advantages to alkylating amylenes are:
- It helps reduce the RVP of the FCC gasoline
- It helps reduce the RVP of the entire gasoline pool (although not as much as it might appear on the surface due to the Hydrogen Transfer Reaction)
- It reduces the total olefin content of the gasoline pool.
- It increases the volume of gasoline produced from the amylenes (or another way to look at it is that it allows the refiner to convert some iso-butane into gasoline)
Some challenges are:
- Dealing with the increased amount and type of feed contaminants (sulfur and diolefins)
- Increased ASO production – difficulty maintaining acid purity
- More olefin feed means lower iso-butane/olefin ratio for most units
- Increased iC5 production in the Alky (due to the Hydrogen Transfer Reaction). This can cause higherRVP of the alkylate or more iC5 in the n-butane produc